Electrocleaning in Electroplating

31 Jul.,2025

Electrocleaning  is an electrochemical cleaning process used in electroplating to remove stubborn contaminants (oils, oxides, and organic residues) from metal surfaces. It enhances adhesion and plating quality by combining alkaline chemistry with electrical current.

 

Author: Marisa

1. Introduction

Electrocleaning  is an electrochemical cleaning process used in electroplating to remove stubborn contaminants (oils, oxides, and organic residues) from metal surfaces. It enhances adhesion and plating quality by combining alkaline chemistry with electrical current.


2. Purpose

Removes remaining oils & oxides after alkaline soak cleaning.

  • Activates the surface for better plating adhesion.

  • Provides a microscopically clean surface for uniform plating.

  • Used for critical applications (e.g., automotive, aerospace, electronics).


3. Types of Electrocleaning

Type Mechanism Applications
Anodic Electrocleaning
(阳极电解清洗)
Workpiece = Anode (+)
(Oxidation removes contaminants & light etching)
Steel, nickel, copper alloys
Cathodic Electrocleaning
(阴极电解清洗)
Workpiece = Cathode (-)
(Hydrogen gas scrubs away dirt)
Zinc, aluminum, sensitive metals
Periodic Reverse (PR) Cleaning
(周期换向电解清洗)
Alternates between anodic & cathodic cycles High-precision plating

4. Typical Process Parameters

Parameter Range Notes
Voltage 3–12 V (DC) Higher voltage = more aggressive cleaning
Current Density 3–10 A/dm² Adjust based on metal type
Temperature 50–80°C (122–176°F) Improves conductivity
Time 30 sec – 5 min Longer for heavy contamination
Solution Alkaline (NaOH, Na₂CO₃ + additives) pH 10–13

5. Key Process Steps 

  1. Pre-Cleaning (Soak or spray cleaning to remove bulk oils).

  2. Electrocleaning (Immerse part, apply current).

  3. Rinsing (Immediately after to remove residues).

  4. Acid Activation (Optional, for oxide removal).


6. Advantages

✔ Deep cleaning – Removes sub-surface contaminants.
✔ Surface activation – Improves plating adhesion.
✔ Uniformity – Better than mechanical cleaning.


7. Limitations 

✖ Hydrogen Embrittlement (Cathodic cleaning can introduce H₂ into steel).
✖ Etching Risk (Anodic cleaning may over-etch sensitive metals).
✖ Higher cost vs. soak cleaning (energy & equipment).


8. Troubleshooting

Issue Possible Cause Solution
Poor Plating Adhesion Inadequate cleaning time/current Increase current density or time
White Stains Residual alkali Improve rinsing
Pitting/Etching Excessive anodic cleaning Reduce time/voltage or switch to cathodic

9. Comparison with Soak Cleaning

Feature Electrocleaning Soak Cleaning
Cleaning Power Stronger (electrochemical action) Moderate (chemical only)
Speed Faster (30 sec – 5 min) Slower (5–20 min)
Cost Higher (energy & equipment) Lower
Applications High-precision plating General-purpose cleaning

Conclusion

Electrocleaning is a high-efficiency pre-plating process for critical applications. Proper selection of anodic/cathodic modecurrent density, and solution composition ensures optimal results.

Next Step?

  • For hydrogen-sensitive metals (e.g., high-strength steel), use anodic or PR cleaning.

  • For soft metals (e.g., zinc, aluminum), prefer cathodic cleaning.